In which movie does the above screenshot appear? What science fiction techniques were highly used to create this movie?

This screenshot comes from The Matrix. The Matrix used a combination of stunts, CGI, slow motion, and compositing helps to create movie sequences like this one.

Explanation:

Answer on Edge

photography had emerged as an elite art pursued by a few creative individuals for a few wealthy patrons. but now, said bauldelaire, it was succumbing to "the great industrial madness of our times." it was becoming a mass production industry that catered to middle-class tastes, including a taste for gadgetry. the stereoscope, the first 3d imaging system, had turned looking at photographs into parlor entertainment. a "thousand hungry eyes were bending over the peepholes of the stereoscope as though they were the attic-windows of the infinite.