Why are the warmest hours of the day usually mid- to late afternoon?

The sun is closest to the earth during those times

A  reaction  in which  energy  is  released  to the surroundings is called an exothermic  reaction. in this type of  reaction  the enthalpy, or stored  chemical energy, is lower for the products than the reactants. when ammonium nitrate is dissolved in water,  energyis  absorbed  and the water cools.