Using only the 1h nmr spectrum of the crude nitration product, determine if the product is mostly ortho-, meta-, or para- substituted. (note: jortho= ~8 hz, jmeta= ~3 hz and jpara = ~1 hz. also aromatic protons ortho to no2 or c=o groups are generally downfield.) a. major product(s) = b. describe how you came to your conclusi

In methyl benzoate there are 3 types of 1 H proton. The two ortho to the C=O group is a doublet at 8 ppm the 2 metal to the C=O is a multiple at 7.5 ppm and one para to the C=O is a multiplet at 7.5 ppm.

On nitration the ortho will probably show two signal one being a single with 3 proton integration and one a doublet with 1 H integration

The meta will show a highly down field singlet (coresponding to 1 proton), two unequal doublets (corresponding to 1 H each) and one multiplets (corresponding to 1H). This is the major product as seen from the 1H NMR.

The para isomer will come as two doublets which will be very close to each other there is a small signal for this set between 8.2 and 8.3 ppm.

explanation:

two years ago, when picking flowers in the mountains back of yosemite valley, i found a book. it was blotted and storm-beaten; all of its outer pages were mealy and crumbly. the paper seemed to dissolve like the snow beneath which it had been buried, however; many of the inner pages were well preserved. and although all were more or less stained and torn, whole chapters were easily readable. this is the condition of the great open book of yosemite glaciers today; its granite pages have been torn and blurred by the same storms that wasted the castaway book.

two years ago, when picking flowers in the mountains back of yosemite valley; i found a book. it was blotted and storm-beaten, all of its outer pages were mealy and crumbly. the paper seemed to dissolve like the snow beneath which it had been buried, however, many of the inner pages were well preserved. and although all were more or less stained and torn; whole chapters were easily readable. this is the condition of the great open book of yosemite glaciers today, its granite pages have been torn and blurred by the same storms that wasted the castaway book.