*what are some of the safety concerns for barium sulfate & barium sulfide? explain

BaSO₄ is relatively harmless, but BaS is highly toxic.

BaSO₄ is quite insoluble (240 µg/100 mL). It is a mild irritant in cases of skin contact and inhalation. However, it is safe enough that health professionals ask patients to drink a suspension of BaSO₄. The Ba is opaque to X-rays, so it makes the stomach and intestines more visible to radiographers.

BaS is soluble (7.7 g/100 mL). It reacts slowly with water and more rapidly in the acid conditions of the stomach to release H₂S.

BaS + 2HCl ⟶ BaCl₂ + H₂S

An H₂S concentration of 60 mg/100 mL can be fatal within 30 min.

Don’t eat barium sulfide!