Why is the zone of aeration termed as such

Consider the reduction reactions and their equilibrium constants. cu+(aq)+e−↽−−⇀cu(s)pb2+(aq)+2e−↽−−⇀pb(s)fe3+(aq)+3e−↽−−⇀fe(=6.2×108=4.0×10−5=9.3×10−3 cu + ( aq ) + e − ↽ − − ⇀ cu ( s ) k =6.2× 10 8 pb 2 + ( aq ) +2 e − ↽ − − ⇀ pb ( s ) k =4.0× 10 − 5 fe 3 + ( aq ) +3 e − ↽ − − ⇀ fe ( s ) k =9.3× 10 − 3 arrange these ions from strongest to weakest oxidizing agent.

What amount of heat is exchanged when 106.2 grams of substance y goes from a liquid at 35 degrees celsius to a solid at the same temperature? melting point of substance y = 35 degrees c; δhvaporization = 3.67 j/mol; δhfusion = 3.30 j/mol. mwsubstance y = 28.22 g/mol. −12.4 j −3.51 x 102 j 1.24 x 101 j 351 j

Iwould appreciate if someone could me.