Idont get chemistry as much as i've only just started and i dont know how to separate all these matters

Why doesn't heat added to water make the tempature rise above 100c

The plant food contains nh4)3po4 what tests would you run to verify the presence of the nh4 ion and the po4 ion

Using this reversible reaction, answer the questions below: n2o4 2no2 (colorless) (reddish-brown) -as the temperature increased, what happened to the n2o4 concentration? -was the formation of reactants or products favored by the addition of heat? -which reaction is exothermic? right to left or left to right? -if the change of enthalpy of this reaction when proceeding left to right is 14 kcal, which chemical equation is correct? n2o4 2no2 + 14 kcal n2o4 2no2, hr = +14 kcal n2o4 + 14 kcal 2no2 n2o4 2no2, hr = -14 kcal