A75.0-ml volume of 0.200 m nh3 (kb=1.8×10−5) is titrated with 0.500 m hno3. calculate the ph after the addition of 28.0 ml of hno3.

A) Initial moles of NH3 = 75/1000 x 0.200 = 0.015 mol

Moles of HNO3 added = 28/1000 x 0.500 = 0.014 mol

NH3 + HNO3 => NH4+ + NO3-

Moles of NH3 left = 0.015 - 0.014 = 0.001 mol

Moles of NH4+ = 0.014 mol

Ka(NH4+) = Kw/Kb(NH3)

= 10-14/1.8 x 10-5 = 5.556 x 10-10

Henderson-Hasselbalch equation:

pH = pKa + log([NH3]/[NH4+])

= -log Ka + log(moles of NH3/moles of NH4+) since volume is the same for both

= -log(5.556 x 10-10) + log(0.0065/0.014)

= 8.14

Answer : The pH after the addition of 28.0 ml of is, 8.1

Explanation :

First we have to calculate the moles of and .

The balanced chemical reaction is,

Moles of left = Initial moles of - Moles of added

Moles of left = 0.015 - 0.014 = 0.001 mole

Moles of = 0.014 mole

Now we have to calculate the .

Now we have to calculate the

Now we have to calculate the pH by using Henderson-Hasselbalch equation.

Now put all the given values in this expression, we get:

Therefore, the pH after the addition of 28.0 ml of is, 8.1

answer: the value of enthalpy change will be -152.80 kj.

solution:

pressure = 1atm , temperature = = 298 k

given that pressure and temperature are same in both gases , the number of moles of both gases can be determined by the ideal gas equation.

according to reaction 3 moles no are reacting with 1 mol of ,then 0.49 mol of no will react with moles of ozone that is 0.16 moles of ozone. since, no is limiting reagent and is an excessive reagent.

enthalpy change for the reaction between the given volumes of the gases is :