Both 1,2−dihydronaphthalene and 1,4−dihydronaphthalene may be selectively hydrogenated to 1,2,3,4−tetrahydronaphthalene. one of these isomers has a heat of hydrogenation of 101 kj/mol (24.1 kcal/mol), and the heat of hydrogenation of the other is 113 kj/mol (27.1 kcal/mol). match the heat of hydrogenation with the appropriate dihydronaphthalene.

1,4-dihydro = 113 kJ·mol⁻¹

1,2-dihydro = 101 kJ·mol⁻¹

Explanation:

In 1,4-dihydronaphthalene, the 2,3-double bond is isolated from the benzene ring.

In 1,2-dihydronaphthalene, the 3,4-double bond is conjugated with the benzene ring.

Thus, 1,2-dihydronaphthalene is partially stabilized by resonance interactions between the ring and the double bond (think, styrene).

1,2-Dihydronaphthalene is at a lower energy level because of this stabilization.

The heat of hydrogenation of 1,2-dihydronaphthalene is therefore less than that of the 1,4-isomer when each is hydrogenated to the common product, 1,2,3,4-tetrahydronaphthalene.

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