Briefly explain the difference between mass transfer coefficient and diffusion coefficient using a suitable diagram (only a brief sketch) of the diffusion layer model for a reaction between aqueous species and a solid (see lecture slides) (a) (b)assume that the mass transfer of a controls the rate of reaction between a and b at each of the three interphases (i), (ii) and (iii) shown below. comment with reasons (one sentence only in each case) regarding the phase through which the transfer of a will control the reaction rate (solid, gas or aqueous) (iii) organic (b) aqueous (a) solid (b) gas (a) aqueous (a) aqueous (b) (c) nickel dissolves from millerite (nis) in an oxygenated sulfuric acid solution at 80 °c. list the important steps, which may control the leaching of nickel from the suspended nis particles in this solution according to the reaction

13. calculate the initial concentration (before precipitation) of carbonate ions after the addition of each 0.05 ml of solution b to the 1.00 l beaker of solution a. divide the work among group members and write the answers in the table in model 3. assume the volume change as solution b is added is negligible. 14. notice the initial concentrations of zn2+ - and cu2+ in the table in model 3. a. explain how these were obtained from the data in model 2. b. as solution b is added and precipitates form, do these initial concentrations change? 15. use the data in model 2 to indicate the presence of precipitate (either znco3 or cuco3) after each 0.05 ml addition of solution b in model 3. 16. use the initial concentrations of carbonate ions and zinc ions to calculate the reaction quotient, qsp for the zinc carbonate scenarios in model 3. divide the work among group members and write the answers in the table in model 3. 17. use the initial concentrations of carbonate ion and copper(ii) ions to calculate the qsp for the copper(ii) carbonate scenarios in model 3. divide the work among group members and write the answers in the table in model 3.

Which of the dna typing techniques do you think you would choose if you had to analyze a dna sample? why?

7. using your knowledge of colligative properties explain whether sodium chloride or calcium chloride would be a more effective substance to melt the ice on a slick sidewalk. use 3 – 4 sentences in your explanation. 8. when a 2.5 mol of sugar (c12h22o11) are added to a certain amount of water the boiling point is raised by 1 celsius degree. if 2.5 mol of aluminum nitrate is added to the same amount of water, by how much will the boiling point be changed? show all calculations leading to your answer or use 3 – 4 sentences to explain your answer. 9. if 5.40 kcal of heat is added to 1.00 kg of water at 100⁰c, how much steam at 100⁰c is produced? show all calculations leading to an answer. 10. the freezing of water at 0⁰c can be represented as follows: h2o (l) ↔ h2o(s) the density of liquid water is 1.00 g/cm3. the density of ice is 0.92 g/cm3. in 3 – 4 sentences explain why applying pressure causes ice to melt.