Chemistry, 01.08.2019 01:20 bryce59

Consider the following reaction: co(g)+2h2(g)⇌ch3oh(g) kp=2.26×104 at 25 ∘c. calculate δgrxn for the reaction at 25 ∘c under each of the following conditions. pch3oh= 1.4 atm ; pco=ph2= 1.2×10−2 atm

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Answer from: madi1820

Answer : The value of $\Delta G_{rxn}$ is, 8.867kJ/mole

Explanation :

The formula used for $\Delta G_{rxn}$ is:

$\Delta G_{rxn}=\Delta G^o+RT\ln Q$ ............(1)

where,

$\Delta G_{rxn}$ = Gibbs free energy for the reaction

$\Delta G_^o$ = standard Gibbs free energy

R = gas constant = 8.314 J/mole.K

T = temperature = 25^oC=273+25=298K

Q = reaction quotient

First we have to calculate the $\Delta G_^o$ .

Formula used :

$\Delta G^o=-RT\times \ln K_p$

Now put all the given values in this formula, we get:

$\Delta G^o=-(8.314J/mole.K)\times (298K)\times \ln (2.26\times 10^{4})$

$\Delta G^o=-24839.406J/mole=-24.83\times 10^3J/mole=-24.83kJ/mole$

Now we have to calculate the value of 'Q'.

The given balanced chemical reaction is,

$CO(g)+2H_2(g)\rightarrow CH_3OH(g)$

The expression for reaction quotient will be :

$Q=\frac{(p_{CH_3OH})}{(p_{CO})\times (p_{H_2})^2}$

In this expression, only gaseous or aqueous states are includes and pure liquid or solid states are omitted.

Now put all the given values in this expression, we get

$Q=\frac{(1.4)}{(1.2\times 10^{-2})\times (1.2\times 10^{-2})^2}$

$Q=8.1\times 10^{5}$

Now we have to calculate the value of $\Delta G_{rxn}$ by using relation (1).

$\Delta G_{rxn}=\Delta G^o+RT\ln Q$

Now put all the given values in this formula, we get:

$\Delta G_{rxn}=-24.83kJ/mole+(8.314\times 10^{-3}kJ/mole.K)\times (298K)\ln (8.1\times 10^{5})$

$\Delta G_{rxn}=8.867\times 10^3J/mole=8.867kJ/mole$

Therefore, the value of $\Delta G_{rxn}$ is, 8.867kJ/mole

Answer from: Quest

a mercury barometer is a device that uses the physical properties of mercury in a tube to measure barometric pressure. mercury barometers are used for : -

1. measurement of atmospheric pressure

2. determining the altitude of a place

3. weather forecasting

4. calibration and checking of aneroid barometers

5. application in fluid mechanics

6. measurement of pressure in aircrafts

7. surface weather analysis

8. preparation of barographs

9. usage in physical sciences like physics, astronomy & chemistry

10. preparation of aircraft altimeters

characteristics of mercury barometer : -

1.used to define and measure atmospheric pressure.

2.on the average at sea level the column of mercury rises to a height of about 760 mm.

3.this quantity is equal to 1 atmosphere.

4.it is also known as standard atmospheric pressure.

5.a barometer in which the weight of a column of mercury in a glass tube with a sealed top is balanced against that of the atmosphere pressing on an exposed cistern of mercury at the base of the mercury column, the height of the column varying with atmospheric pressure.

Write 15 uses of a mercury barometer along with its characterestics

Answer from: Quest

the answer would be b i believe

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Consider the following reaction: co(g)+2h2(g)⇌ch3oh(g) kp=2.26×104 at 25 ∘c. calculate δgrxn for th...

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