consider the gas phase dissociation of iodine i2(g)â2i(g)
the thermal wavelength of 127i at t=298k.= 8.97*10^-12 m
the translational partition function of 127i at t=298k. p=1.00atm and v=24.4l. = 3.38*10^31
calculate
a) calculate the rotational partition function of i2 at t=298k. assume î¸rot=0.0537k
b) calculate the vibrational partition function of i2 att=298k if the vibrational temperature of i2 is î¸vib=308k
c) using the result from part b, calculate the partition function of i. assume the ground electronic state degeneracy of i is g1=4.
d) calculate the partition function of i2. assume g1=1 and de=150.3kj/mol
e) calculate the equilibrium constant for the dissociation of i2 at t=298k. assume n=6.02*1023.
f) calculate îgo for the dissociation of i2 at t=298k.
g) how accurate is this statistical calculation? for i(g) îgof=70.2kj/mol. for i2(g) îgof=19.3kj/mol. calculate îgoreac for the dissociation of i2(g).