Explain the role of the laws of thermodynamics in various engineering processes as regards feasibility. in the explanation write about the first and second law in terms of their application mentioned above; indicate their limitations.

vanderwaal's forces of attraction are the electrostatic intermolecular forces that exist in a molecule due to the temporary or permanent dipoles that are developed in a molecule. in , the major intermolecular forces are dipole-dipole interactions as the molecule is polar (bent structure). so the vanderwaal's forces of interaction in between molecules are the permanent dipole-dipole interactions that develop due to the dipole that exists in between the polar h - s bond. the positively charged hydrogen atom is attracted towards the negative end of the dipole that is sulfur of the adjacent molecule. therefore, these forces of attraction are relatively stronger than that of london dispersion forces that exist in non polar molecules.

some of the qualities most frequently associated with the baroque are grandeur, sensuous richness, drama, vitality, movement, tension, emotional exuberance, and a tendency to blur distinctions between the various arts.