Chemistry, 28.09.2019 01:20 kathrynsalomon

Write the nernst equation for the following half-reaction and find e when ph = 3,00 and paul=1.00 mbar. as(s) + 3h* +3e a sh, (g); e = -0.238 v (a) -0.356 v (b) +0.556 v (c) +0.356 v (d) -0.556 v answer

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Answer from: Quest

i believe the answer is 5,000

Answer from: Quest

the missing options are :

(1) lower boiling point and a lower freezing point(2) lower boiling point and a higher freezing point(3) higher boiling point and a lower freezing point(4) higher boiling point and a higher freezing point

answer : the correct answer is option (3) higher boiling point and a lower freezing point

explanation :

when a non volatile solute is added to a solvent like water, it results in elevation of boiling point.

let us find the increase in boiling point of water when cacl₂ is added to water to make a solution of 1 m

step 1 : find molality of the solution

let us assume we have 1 l of solution.

$m = \frac{moles (solute)}{l ( solution)}$

$1 m = \frac{moles (cacl_{2})}{1 l }= 1 mol cacl_{2}$

let us convert this to grams of cacl₂.

molar mass of cacl2 is 111 g/mol

grams of cacl₂ = $1 mol \times \frac{111g}{mol} = 111 g cacl_{2}$

mass of solute = 111 g

assuming density of solution same as water which is 1g/ml we have ,

mass of solution = density * volume

mass of solution = $\frac{1g}{ml} \times 1000 ml = 1000 g$

mass of solution = mass of solvent + mass of solute

mass of solute = 1000g - 111g

mass of solute 889 g = 0.889 kg

the molality of the solution can be calculated as

$molality = \frac{mol (solute)}{kg ( solvent)}$

$molality = \frac{1mol}{0.889kg}$

molality = 1.12 m

step 2 : find boiling point elevation.

the elevation in boiling point is calculated as

$\bigtriangleup t_{b} = i \times k_{b} \times m$

here δtb = boiling point elevation

i = vant hoff factor which is the number of ions formed by the solute .

cacl₂ dissociates as $cacl_{2} \rightarrow ca^{2+} + 2 cl^{-}$

it forms 3 ions . therefore,

i = 3

m = molality which is 1.12 m

kb is constant for a given solvent. for water it is 0.512

$\bigtriangleup t_{b} = 3 \times 0.512 \times 1.12$

$\bigtriangleup t_{b} = 1.7$

the boiling point of water increases by 1.7 °c

step 3: find freezing point depression.

when a non volatile solute is added to water, it results in decrease in freezing point.

the formula to find freezing point depression is

$\bigtriangleup t_{f} = i \times k_{f} \times m$

kf is constant for water and its value is 1.86

$\bigtriangleup t_{f} = 3 \times 1.86 \times 1.12$

$\bigtriangleup t_{f} = 6.2$

the freezing point of water decreases by 6.2 °c

therefore we can say that, the solution will have a higher boiling point and a lower freezing point

Answer from: Quest

answer is: empirical formula is tl₂o. if we use 100 grams of compound, tha:

m(tl) = 96.2% · 100 g ÷ 100%.

m(tl) = 96.2 g.

n(tl) = m(tl) ÷ m(tl). n(tl) = 96.2 g ÷ 204.4 g/mol.

n(tl) = 0.47 mol. m(o) = 3.77 g. n(o) = m(o) ÷ m(o). n(o) = 3.77 g ÷ 16 g/mol. n(ag) = 0.235 mol. n(tl) . n(o) = 0.47 mol : 0.235 mol /0.235. n(tl) . n(o) = 2 : 1.

m(tl₂o) = 204.4 g/mol · 2 + 16 g/mol = 424.8 g/mol.

m(compound) = 456. 8 g/mol - 424.8 g/mol = 32 g/mol ( 2 oxygens); tl₂o₃.

Answer from: Quest

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Write the nernst equation for the following half-reaction and find e when ph = 3,00 and paul=1.00 mb...

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