An ideal gas, initially at 30oc and 100 kpa, undergoes the following cyclic processes in a closed system: (a) in mechanically reversible processes, it is first compressed adiabatically to 500 kpa then cooled at a constant pressure of 500kpa to 30oc, and finally expanded isothermally to its original state. b). the cycle ravers exactly the same changes of the state, but each step is irreversible with an efficiency of 80% compared with the corresponding mechanically reversible process. note: the initial step can no longer be adiabatic. calculate q, w, δu, and δh for each step of the process and for the cycle. take cp= 3.5r.

In a sample of oxygen gas at room temperature, the average kinetic energy of all the balls stays constant. which postulate of kinetic molecular theory best explains how this is possible? a. attractive forces between gas particles are negligible because the particles of an ideal gas are moving so quickly. b. collisions between gas particles are elastic; there is no net gain or loss of kinetic energy. c. gases consist of a large number of small particles, with a lot of space between the particles. d. gas particles are in constant, random motion, and higher kinetic energy means faster movement.

Lem 2 the data below are for the system ethyl propyl ether (1)-chloroform (2) at 0.5 bar. use the data to answer the following questions (all questions refer to p d 0: 5 bar). a) what are the boiling points of the pure components at 0.5 bar? b) a mixture with the overall composition z1 d 0: 1 is brought to 47.6ä±c, 0.5 bar. what is the phase? c) 100 mole of a mixture with z1 d 0: 1 (state a) is mixed with 22 mole of pure ethyl propyl ether vapor (state b). the mixing takes place at 47.6 ä±c, 0.5. bar. what is the phase of the resulting mixture (state c)? if the state is a v/l mixture report the number of moles and mole fractions in each phase. d) plot the txy graph and show states a, b and c. the graph must be done by computer and should be properly annotated. ethyl propyl ether (1) - chloroform (2) at 0.5 bar t ( ä±c) x1 y1 t ( ä±c) x1 y1 42.9 0.000 0.000 49.0 0.470 0.455 43.0 0.020 0.010 49.1 0.520 0.520 43.9 0.065 0.029 48.9 0.567 0.592 45.4 0.156 0.089 48.3 0.652 0.720 46.4 0.215 0.142 47.6 0.745 0.815 47.6 0.296 0.223 46.7 0.822 0.872 48.3 0.362 0.302 45.7 0.907 0.937 48.7 0.410 0.375 44.6 1.000

16. why must the number of electrons lost equal the number of electrons gained in every redox reaction? use 3 – 4 sentences in your own words to address this question. 18. what type of radiation is emitted when chromium-51 decays into manganese-51? show the nuclear equation that leads you to this answer. 19. a radioactive nucleus alpha decays to yield a sodium-24 nucleus in 14.8 hours. what was the identity of the original nucleus? show the nuclear equation that leads you to this answer.