Chemistry, 29.10.2019 05:31 stuckonquestions

Abuffer contains 0.19 mol of propionic acid (c2h5cooh) and 0.26 mol of sodium propionate (c2h5coona) in 1.20 l. you may want to reference (pages 721 - 729) section 17.2 while completing this problem. part a what is the ph of this buffer? express the ph to two decimal places. php h = nothing request answer part b what is the ph of the buffer after the addition of 0.02 mol of naoh? express the ph to two decimal places. php h = nothing request answer part c what is the ph of the buffer after the addition of 0.02 mol of hi? express the ph to two decimal places.

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Answer from: dpazmembreno

Explanation:

It is known that $pK_{a}$ of propionic acid = 4.87

And, initial concentration of propionic acid = $\frac{0.19}{1.20}$

= 0.158 M

Concentration of sodium propionate = \frac{0.26}{1.20}[/tex]

= 0.216 M

Now, in the given situation only propionic acid and sodium propionate are present .

Hence, pH = $pK_{a} + log(\frac{[salt]}{[acid]})$

= $4.87 + log \frac{0.216}{0.158}$

= 4.87 + log (1.36)

= 5.00

Therefore, when 0.02 mol NaOH is added then,

Moles of propionic acid = 0.19 - 0.02

= 0.17 mol

Hence, concentration of propionic acid = $\frac{0.17}{1.20 L}$

= 0.14 M

and, moles of sodium propionic acid = (0.26 + 0.02) mol

= 0.28 mol

Hence, concentration of sodium propionic acid will be calculated as follows.

$\frac{0.28 mol}{1.20 L}$

= 0.23 M

Therefore, calculate the pH upon addition of 0.02 mol of NaOH as follows.

pH = $pK_{a} + log(\frac{[salt]}{[acid]})$

= $4.87 + log \frac{0.23}{0.14}$

= 4.87 + log (1.64)

= 5.08

Hence, the pH of the buffer after the addition of 0.02 mol of NaOH is 5.08.

Therefore, when 0.02 mol HI is added then,

Moles of propionic acid = 0.19 + 0.02

= 0.21 mol

Hence, concentration of propionic acid = $\frac{0.21}{1.20 L}$

= 0.175 M

and, moles of sodium propionic acid = (0.26 - 0.02) mol

= 0.24 mol

Hence, concentration of sodium propionic acid will be calculated as follows.

$\frac{0.24 mol}{1.20 L}$

= 0.2 M

Therefore, calculate pH upon addition of 0.02 mol of HI as follows.

pH = $pK_{a} + log(\frac{[salt]}{[acid]})$

= $4.87 + log \frac{0.2}{0.175}$

= 4.87 + log (0.114)

= 4.98

Hence, the pH of the buffer after the addition of 0.02 mol of HI is 4.98.

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Abuffer contains 0.19 mol of propionic acid (c2h5cooh) and 0.26 mol of sodium propionate (c2h5coona)...

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