How are atoms and the periodic table related?

The problem here is that according to aufbau principle before 3d orbital 4s subshell comes.after filling 3p orbital with electrons you have 4 electrons left, you place two in 4s with opposite spin and the other two in 3d in any of its two orbitals of total five orbitals with the same spin.

Standing in the sunlight and feeling the heat on your face (uv radiation is entering the skin, converting to infrared radiation, and is absorbed by your tissues)orstanding near a fire and feeling the heat on your skin (infrared radiation transfer)