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Why is an elements atomic mass not listed as a whole number on the periodic table

Ariver current has a velocity of 5km/h relative to the shore, and a boat moves in the same direction as the current at 5 km/h relative to the river. how can the velocity of the boat relative to the shore be calculated?

If you used the method of initial rates to obtain the order for no2, predict what reaction rates you would measure in the beginning of the reaction for initial concentrations of 0.200 m, 0.100 m, & 0.050 m no2.