1-propynyllithium reacts with (r, r)-2,3-dimethyloxacyclopropane in a stereoselective reaction. draw a curved arrow mechanism and the missing intermediate and product, clearly showing stereochemistry with a wedge and hashed bond at each stereocenter.

a). in this case, dh> 0 and sd> 0. if t becomes larger, the term "-tds" will become more negative. at some point, it is possible that -dts will be more negative than the dh is positive, and the reaction will become spontaneous. this is probably the correct answer, but you should look at all of the other possibilities and make sure of that.