Chemistry, 28.12.2019 03:31 lsrgb

In a reaction between 6.0 g of oxygen gas, 4.0 g of hydrogen gas, and 5.0 g of solid sulfur at standard temperature and pressure to make h₂so₄, which is the limiting reagent?

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Answer from: wananikwecurley99

The limiting reagent is the O₂

Explanation:

We can think, this reaction

2O₂(g) + H₂(g) + S(s) → H₂SO₄

Mole of each = Mass / molar mass

6 g / 32 g/m = 0.187 mole O₂

4g / 2 g/m = 2 mole H₂

5g / 32.06 g/m = 0.156 mole S

Ratio between reactants is 2:1:1, 1:2:1, 1:1:2

For 2 mole of O₂, I need to react 1 mol of H₂ and 1 mol of S

0.187 mole of O₂, I need (the half)

0.093 mole of H₂ and 0.093 mole of S

For 1 mole of H₂, I need to react 2 mole of O₂ and 1 mol of S

2 mole of H₂, I need (the double of O₂ and the same for S)

4 mole of O₂ ; 2 mole of S

For 1 mol of S, I need to react 1 mol of H₂ and 2 mole of O₂

0.156 mole I need the same amount for H₂ and the double for O₂

0.156 mole of H₂ and 0.312 mole of O₂

In both cases, I can't make react, all the mass of oxygen, so this is the limiting reagent.

Answer from: Quest

here we have to get the change of moles on decrease the volume of the reaction in gas phase.

the per the given options it will decrease by (d) 11-50%

we know, on decreasing the volume of the gas phase reaction the reaction moves to the product side.

the reaction: so₂cl₂ (g) = so₂ (g) + cl₂ (g) total

the moles at equilibrium: 1 - α α α = 1+α

concentrations: 1 - α α α = 1 + α

(concentration = moles/volume, as volume is 1 l)

(where α is the degree of dissociation)

now the dissociation constant in terms of concentration is :

$k_{c}$ = $\frac{[so2cl2] x [cl2]}{[so2cl2]}$

or, $\frac{\alpha ^{2} }{(1-\alpha)v }$

or, $k_{c}$ = $\frac{\alpha ^{2} }{(1-\alpha) }$ (at v = 1l)

the reaction: so₂cl₂ (g) = so₂ (g) + cl₂ (g) total

the moles at equilibrium: 1 - α α α = 1+α

concentrations: (1 - α)/0.5 α/0.5 α/0.5 = (1 + α)/0.5

thus, the dissociation constant in terms of concentration is :

$\frac{[so2cl2] x [cl2]}{[so2cl2]}$

or, $\frac{\alpha ^{2} }{(1-\alpha)0.5 }$

$\frac{\alpha ^{2} }{(1-\alpha) }$ = $\frac{\alpha ^{2} }{(1-\alpha) 0.5}$

so, the change of 1 : 1/0.5

or, 1: 2

thus it will decrease by 50%.

or, as per the given options it will decrease by 11-50%

Answer from: Quest

the answer is the first option

explanation:

just googled it m8. not that hard

lol

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In a reaction between 6.0 g of oxygen gas, 4.0 g of hydrogen gas, and 5.0 g of solid sulfur at stand...

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