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why the total energy of electron is negative

Electrons are always marked negative Hence electronic energy is also always taken as negative. It is because when an electron is at infinite distance from nucleus , there the kinetic energy of that electron can not be calculated. So, it is taken to be zero . ... And thus the energy of electron becomes less negative

definition

                    entropy is a measure of the randomness or the extent of disorder of a chemical process.

                      enthalpy is a measure of the heat change of a reaction occurring at a constant pressure.

measurement units:

                        entropy is measured in joule per kelvin (jk⁻¹)   whereas enthalpy is measured in joule per mole (jmol⁻¹)

requirements:

                            entropy has no requirements or limits, and its change is measured by the division between the heat change of the chemical process and the temperature.

                              in contrast, enthalpy can only be related to the heat change of the reaction under standard conditions.