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Chemistry, 14.01.2020 21:31 wingleo12

Suggest a reasonable explanation for each of the following observations:

(a) the second-order rate constant k for saponification (basic hydrolysis) of ethyl trifluoroacetate is over 1 million times greater than that for ethyl acetate (25°c).
(b) the second-order rate constant for saponification of ethyl 2,2-dimethylpropanoate, (ch3)3cco2ch2ch3, is almost 100 times smaller than that for ethyl acetate (30°c).
(c) the second-order rate constant k for saponification of methyl acetate is 100 times greater than that for tert-butyl acetate (25°c).
(d) the second-order rate constant k for saponification of methyl m-nitrobenzoate is 40 times greater than that for methyl benzoate (25°c).

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