Chemistry, 16.01.2020 04:31 durham953

Can i get with this,
the enclosed cabin of a submarine has a volume of 2.4 × 105 liters, a temperature of 312 k, and a pressure of 116 kpa. as people in the cabin breathe, carbon dioxide gas, co2(g), can build up to unsafe levels. air in the cabin becomes unsafe to breathe when the mass of co2(g) in this cabin exceeds 2156 grams. show a numerical setup for calculating the pressure in the submarine cabin if the cabin temperature changes to 293 k.
!

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Answer from: vultuxx

Pressure in the submarine when the temperature is changed to 293 K is 108.9 K Pa

Explanation:

Pressure in the submarine = 108.9 kPa

Volume, V = 2.4 * 10^5 L

Pressure, P = 116k Pa

Temperature, T = 312 K

Ideal gas law: PV = nRT or n = PV / RT

So, moles of gas, n =116 KPa * 2.4 * 10 ^5L / 8.314 LK Pa K^-1 *312 K

= 1.073 *10^4 mol

when temperature is changed to 293K,

PV = nRT or P = nRT / V

=1.073 *10^4 mol *8.314 LK Pa mol^-1 K^-1 *293 K / 2.4*10^5L

=108.9 K Pa

Pressure in the submarine when the temperature is changed to 293 K is 108.9 K Pa

Answer from: Quest

assuming that your periodic table has eighteen columns, you should highlight the four elements in the third column from the left of the table.

explanation

neutral atoms of elements after calcium contain d electrons. the energy of d orbitals of a particular main shell lies between the energy of the s and p orbitals of the next main shell. for example, electrons in the $3d$ have energy higher than those in the $4 s$ orbital while lower than those of the $4 p$ orbital.

by the aufbau principle, electrons fill orbitals one at a time, starting from those of the lowest energy. the $4s$ orbital is therefore filled right after $3p$ orbitals and before $3 d$ orbitals.

potassium has electron configuration $[\text{ar}] 4 s^{1}$ and calcium $[\text{ar}] 4 s^{2}$ . the s orbital of a main shell holds a maximum of two electrons. the next element would thus have the electron configuration $[\text{ar}] 4 s^{2} \; 3d^{1}$ and satisfy the requirements.

a neutral atom of the element contains three electrons on top of the most recent noble gas element. it should thus be placed in the third column of the periodic table. both scandium and yttrium would satisfy the conditions. an aufbau diagram indicates that the 4f orbital is filled before the 5d. however, it appears that exceptions exists for both lanthanum and actinium. neutral atoms of the two d-block elements also demonstrate the $ns^{2} \; (n-1) p^{1}$ and should be highlighted as well.

Answer from: Quest

Okay this will take 1 hour okay dont forget me.

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