Real gases may be expected to deviate from charles' law at pressures near the temperature.

Real gases deviate from ideal gases when there are conditions such as low temperature and high pressures. Charles' law holds the pressure constant with varying temperature. Given that there is constant pressure, low temperatures cause the deviation from the state of ideality. 

when [oh-] is 10-5  m, and [h3o+] is 10-9  m, the poh is 5 and ph is 9. again in both cases the sum of ph and poh is 14. however, the hydrogen ion concentration is not always going to be equal to exactly 1 x 10 raised to a negative number. for example, we skipped over the value of 2.0 x 10-7.