Calculate the unit cell edge length for an 87 wt% Ag- 13 wt% Pd alloy. All of the palladium is in solid solution, and the crystal structure for this alloy is FCC. Room temperature densities for Ag and Pd are 10.49 g/cm3 and 12.02 g/cm3, respectively, and their respective atomic weights are 107.87 g/mol and 106.4 g/mol. Report your answer in nanometers. nm

Explanation:

   Since the crystal structure is FCC , every unit cell will have 4 atoms . If a be the edge length

average density = 4 x average atomic no / volume of unit cell x N

N is avogadro no or 6.02 x 10²³

average atomic no

= 100 / (87/107.9 +13/106.4) = 107.72

average density = 100 / (87/10.49 + 13/12.02)

= 10.667

10.667 = (4 x 107.72 )/ (a³x 6.02 x 10²³)

a³ = 4 x 107.72 / (10.667 x  6.02 x 10²³)

= 6.71 x 10⁻²³

a = 4.063 x 10⁻⁸ m

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most historians agree that gabriel mouton, the vicar of st. paul’s church in lyons, france, is the “founding father” of the metric system. he proposed a decimal system of measurement in 1670. mouton based it on the length of one minute of arc of a great circle of the earth (now called a nautical mile, 1852 meters). he also proposed the swing-length of a pendulum with a frequency of one beat per second as the unit of length (about 25 cm). a pendulum beating with this length would have been fairly easy to produce, thus facilitating the widespread distribution of uniform standards. over the years, his work was revised, improved, and extended by a number of french scientists.

the political sponsor of weights and measures reform in the french revolutionary national assembly was the bishop of autun, better known as talleyrand. under his auspices, the french academy appointed several committees to carry out the work of developing a usable system of weights and measures for france. one of the committees recommended a decimalized measurement system based upon a length equal to one ten-millionth of the length of a quadrant of the earth’s meridian (i.e., one ten-millionth of the distance between the equator and the north pole).