Hydrogen cyanide, HCN, is prepared from ammonia, air, and natural gas (CH₄), by the following process:

Hydrogen cyanide is used to prepare sodium cyanide, which is used in part to obtain gold from gold-containing rocks. If a reaction vessel contains 11.5g NH₃, 12.0g O₂, and 10.5g CH₄, what is the maximum mass in grams of hydrogen cyanide that could be made, assuming the reaction goes to completion as written?

6.75 g of HCN can be produced by the reaction

Explanation:

Complete reaction is:

2NH₃ (g) + 3O₂ (g) + 2CH₄ (g) → 2HCN (g) + 6H₂O (g)

Let's determine the moles of each reactant:

11.5 g . 1mol / 17g = 0.676 moles of ammonia

12 g . 1 mol / 32g = 0.375 moles of oxygen

10.5 g . 1mol/ 16 g =  0.656 moles of methane

Now is all about rules of three:

2 moles of ammonia reacts with 3 moles of O₂ and 2 moles of methane

0.676 moles of NH₃ may react with:

(0.676 . 3) /2 = 1.014 moles of O₂

(0.676 . 2) / 2 = 0.676 moles of methane

Both can be the limiting reactant.

3 moles of O₂ react with 2 moles of NH₃ and 2 moles of methane

0.375 moles of O₂ will react with:

(0.375 .2) / 3  = 0.375 moles

The same amount for methane, 0.375 moles

2 moles of CH₄ reacts with 3 moles of O₂ and 2 moles of NH₃

0.656 moles of methane would react with 0.656 moles of NH₃

(0.656 . 3 ) /2 = 0.437 moles of O₂   I do not have enough O₂

Oxygen is the limiting reactant → We can work with the reaction now.

Ratio is 3:2. 3 moles of oxygen produce 2 moles of cyanide

0.375 moles of O₂ may produce (0.375 .2 ) / 3 = 0.250 moles

If we convert the moles to mass → 0.250 mol . 27 g / 1mol = 6.75 g

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