One kg of steam in a piston/cylinder device undergoes the following changes of state. Calculate Q and W for each step. a. Initially at 350 kPa and 250°C, it is cooled at constant pressure to 150°C. b. Initially at 350 kPa and 250°C, it is cooled at constant volume to 150°C.

Steam reforming of methane ( ch4) produces "synthesis gas," a mixture of carbon monoxide gas and hydrogen gas, which is the starting point for many important industrial chemical syntheses. an industrial chemist studying this reaction fills a 1.5 l flask with 3.5 atm of methane gas and 1.3 atm of water vapor at 43.0°c. he then raises the temperature, and when the mixture has come to equilibrium measures the partial pressure of carbon monoxide gas to be 1 .0 atm. calculate the pressure equilibrium constant for the steam reforming of methane at the final temperature of the mixture. round your answer to 2 significant digits.