Be sure to answer all parts. Acetone is one of the most important solvents in organic chemistry. It is used to dissolve everything from fats and waxes to airplane glue and nail polish. At high temperatures, it decomposes in a first-order process to methane and ketene (CH2═C═O). At 600°C, the rate constant is 8.7 × 10−3 s−1. (a) What is the half-life of the reaction? Give your answer in scientific notation. 7.97 × 10 s (b) How long does it take for 34% of a sample of acetone to decompose? s (c) How long does it take for 89% of a sample of acetone to decompose? Give your answer in scientific notation. × 10 s

a) 79.66 seconds is the half-life of the reaction.

b) It will take seconds for 34% of a sample of an acetone to decompose.

c) It will take seconds for 89% of a sample of an acetone to decompose.

Explanation:

The decomposition of acetone follows first order kinetics

The rate constant of the reaction = k =

a)

Half life of the reaction =

For the first order kinetic half life is related to k by :

79.66 seconds is the half-life of the reaction.

b)

Let the initial concentration of acetone be =

Final concentration of acetone left after t time = [A]

For the first order kinetic :

Solving for t;

It will take 47.76 seconds for 34% of a sample of an acetone to decompose.

c)

Let the initial concentration of acetone be =

Final concentration of acetone left after t time = [A]

For the first order kinetic :

Solving for t;

It will take seconds for 89% of a sample of an acetone to decompose.

the formula for the conversion of temperature from degree celsius to kelvin is:

the sample of water at is converted to kelvin temperature by using the above formula as:

on comparing the two samples of water at or we can say that at and at respectively. the difference between the temperatures of two samples of water is:

hence, one can say that the sample of water at is greater than the sample of water at by .