For the reversible, one-step reaction A+B<>C+D, the forward rate constant is 52.4 /mol*h and the rate constant for the reverse reaction is 32.1 L/mol*h. The activation energy was found to be 35.2 kJ/mol for the forward reaction and 44.0 kJ. mol for the reverse reaction.

a) What is the equilibrium constant for the reaction?

b) is the reaction exothermic or endothermic?

c) What will be the effect of raising the temperature on the rate constants and the equilibrium constant?

Given the table below, what is the chemical formula for a compound between rb and the nitrate ion no3 -1? nitrate ion no3 -1 phosphate po4 -3 sulfate so4 -2 acetate c2h3o2 -1 ammonium nh4 +1 chromate cro4 -2 carbonate co3 -2 dichromate cr2o7 -2 permanganate mno4 -1 sulfite so3 -2 rbno3 rb2no3 rb(no3)2 rb2(no3)3

Straightforward questions answered in the powerpoint slidesreaction: heating the starting materials under refluxwhat does it mean to heat under reflux? why do we choose water as the reflux solvent? what are boiling chips used for? why do we put a condenser on top of the reaction? why do we add heat and let the reaction stir for 30 minutes? why do we add sulfuric acid to the reaction after it cools as opposed to when it’s still hot? separation: filtration of precipitatewhy don’t we do an aqueous and organic extraction in the separatory funnel? why do you rinse the salicylic acid on the filter with ice cold water? purification: recrystallization of salicylic acid (no hot filtration needed)what is the difference in the amount of room temperature water vs. boiling water needed to dissolve the salicylic acid (assume a 1.2 gram yield of salicylic acid)? remember, in the lab if you need x ml of boiling water to dissolve a solid, then you should add a little more (definitely no more than 1.5 times the theoretical amount) to ensure it doesn’t recrystallize prematurely.analysis: melting point of salicylic acidwhat can you conclude if the melting point of the salicylic acid you just synthesized is 152-155oc and the 1: 1 mix of your product and “synthetic” salicylic acid is 151-154oc?

Question 1 (true/false worth 4 points) (03.06 lc) an induced dipole occurs when a molecule's moving electrons are briefly more concentrated in one place than another, causing the molecule to become temporarily polarized. true false