For each of the following reactions, calculate ΔH∘rxn, ΔS∘rxn, ΔG∘rxn at 25 ∘C. State whether or not the reaction is spontaneous. If the reaction is not spontaneous, would a change in temperature make it spontaneous? If so, should the temperature be raised or lowered from 25 ∘C? 2NH3(g)→N2H4(g)+H2(g) Calculate ΔS∘rxn at 25 ∘C. N2(g)+O2(g)→2NO(g) Calculate ΔS∘rxn at 25 ∘C. 2KClO3(s)→2KCl(s)+3O2(g) Calculate ΔH∘rxn

2b2t

explanation:

2b2t

substituting a hydrogen atom with a halogen in a hydrocarbon:

- the single bond remains single. a is wrong.

- the bond with hydrogen is as strong as with a halogen. c is wrong

- a hydrocarbon is saturated if there is no double bond. we do not know that so d is wrong.

- carbon will always have four valence electrons. e is wrong.

by elimination, the correct answer is b. the boiling point of the new compound increases.