A mixture of 100 kg mol that contains 60 mol % n-pentane (A) and 40 mol % nheptane (B) is vaporized at 101.32 kPa pressure under differential conditions until 40 kg mol are distilled. Use equilibrium data from Example 26.3-2. a. What is the average composition of the total vapor distilled and the composition of the remaining liquid? b. If this same vaporization is done in an equilibrium or flash distillation and 40 kg mol are distilled, what is the composition of the vapor distilled and of the remaining liquid?

Most likely a is the answer - because  you generate   38 atp's but also consume an atp.   each atp gives approx. less than 4 kcal so probably a is the closest answer.

The answer to your question really depends on three things: how much water you have, how cold it is to start out, and how cold the things around it are. water actually freezes when it gets to 32 degrees fahrenheit (0 degrees celsius), but the time it takes to get there may be different.  let's start with the first. if you take two glasses, and fill one with a tiny bit of water, and the other about halfway, then put them both in the freezer, the one with less water will freeze first (you can try this at home, but i recommend using plastic cups and not glass ones).  now let's move on to the second part. let's say you have two glasses, and you fill one with really cold water that has been in the refrigerator, and the other with really hot water from the sink. if you put both of them in the freezer, the one that started out colder will freeze first.  for the third part, let's imagine that you have two glasses with the same amount of water in them, and the water is at the same temperature. imagine putting one outside on a really really cold day in georgia, and having a friend in alaska put one outside on the same day. since it would be so much colder in alaska, the glass of water there would freeze before yours.  so, if you took a tiny bit of really cold water in a glass, and put it outside on a cold day in alaska, it would freeze a lot faster than a big glass of hot water outside on a cold day in georgia.