Aqueous solutions of ammonia (NH3) and hydrogen cyanide (HCN) react to produce ammonium cyanide, (NH4CN) according to the following equilibrium reaction. NH3(aq) + HCN(aq) = NH4+ (aq) + CN (aq) Given the following equilibrium constants, which statement best describes the reaction once equilibrium is established? (Kw - 1.01 x 10-14) NH4+ Ka = 5.6 x 10-10 HCN ka = 4.0 x 10-10 a. reaction is product favored, K<1b. reaction is neither reactant nor product favored reaction is product favored, K>1 c. reaction is reactant favors, K> 1 d. reaction is reactant favors, K<1

Benzonitrile (c6h5cn) is reduced to two different products depending on the reducing agent used. treatment with lithium aluminum hydride followed by water forms k, which has a molecular ion in its mass spectrum at 107 and the following ir absorptions: 3373, 3290, 3062, 2920, and 1600 cm-1. treatment with a milder reducing agent forms l, which has a molecular ion in its mass spectrum at 106 and the following ir absorptions: 3086, 2850, 2820, 2736, 1703, and 1600 cm-1. l shows fragments in its mass spectrum at m/z = 105 and 77. propose structures for k and l and choose an explanation for how this could be concluded.