What is the specific heat of copper if a 105 g sample absorbs 15200 joules and the change in temperature is 377 0C ? (Draw a temperature time graph)

Iknow #2 is d. i just need to know why

Silver tarnishes as silver metal reacts with hydrogen sulfide, h2s, in the air. in this reaction, dark silver sulfide, au2s, covers the surface of silver. when silver is polished, this coating of silver sulfide can be removed from the surface. this makes the silver shiny again. enter the coefficients that balance the tarnishing reaction equation. (type 1 for no coefficient.)

If i initially have a gas at a pressure of 12 atm, a volume of 23 liters, and a temperature of 200 k, and then i raise the pressure to 14 atm and increase the temperature to 300 k, what is the new volume of the gas?