Calculate mass of sulfur that must be burned to give 8g of sulfur dioxide

If anyone would be able to me out with these three questions it would be these are from the chem 2202 course.

Given the following equation: 2a1 + 3mgcl2 --> 2alcl3 + 3mg how many moles of aluminum chloride are produced from 2.5 moles of magnesium chloride?

Asolution is made by dissolving 2.3 moles of sodium chloride (nacl) in 0.155 kilograms of water. if the molal boiling point constant for water (kb) is 0.51 °c/m, what would be the boiling point of this solution? show all the steps taken to solve this problem.