A chemist titrates 80.0mL of a 0.3184M pyridine C5H5N solution with 0.5397M HBr solution at 25°C . Calculate the pH at equivalence. The pKb of pyridine is 8.77.

pH = 2.96

Explanation:

C5H5N + HBr > C5H5N+  + Br-

millimoles of pyridine = 80 x 0.3184 =25.472mM

25.472 millimoles of HBr must be added to reach equivalence point.

25.472  = V x 0.5397

V =25.472/0.5397= 47.197 mL HBr

total volume = 80 + 47.197= 127.196 mL

Concentration of [C5H5N+] = no of moles / volume=

25.472/ 127.196= 0.20M

so,

pOH = 1/2 [pKw + pKa + log C]

pKb = 8.77

pOH = 1/2 [14 + 8.77 + log 0.20]

pOH = 11.0355

pH = 14 - 11.0355

pH = 2.96

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