When might you need something to be artificial rather than real?

Which of the following statements is true about energy quantization at the atomic level? electrons in the outermost orbits are the most stable. electrons in all the orbits around the nucleus have the same amount of energy. electrons in the orbit closest to the nucleus have the least amount of energy. electrons absorb or release the same amount of energy independent of the energy levels.

Areaction is first order. if the initial reactant concentration is 0.0200 m, and 25.0 days later the concentration is 6.25 x 10-4 m, then its half-life is:

Stoichiometry- i need with 14 and 15! an explanation would be appreciated!