At pH0 the more thermodynamically stable species is and the most strongly oxidizing species is . At pH14 the more thermodynamically stable species is and the most strongly oxidizing species is . At pH0 will tend to disproportionate and pH14 will tend to disproportionate. Under acidic conditions mixing Mn3+(aq) and MnO42- (aq) will result in the formation of.

At pH0 the more thermodynamically stable species is lower and the most strongly oxidizing species is higher. At pH14 the more thermodynamically stable species is higher and the most strongly oxidizing species is lower . At pH0 convex curve will tend to disproportionate and pH14 concave curce will tend to disproportionate. Under acidic conditions mixing Mn3+(aq) and MnO42- (aq) will result in the formation of redox oxidation-reduction reaction.

when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol