Places rich in limestone and gypsum have hard water. Why?

Nitrogen (n), phosphorus (p), and potassium (k) are the main nutrients in plant fertilizers. according to an industry convention, the numbers on the label refer to the mass percents of n, p2o5, and k2o, in that order. calculate the n: p: k ratio of a 30: 10: 10 fertilizer in terms of moles of each element, and express it as x: y: 1.0.

1. suppose a reaction mixture, when diluted with water, afforded 300 ml of an aqueous solution of 30 g of the reaction product malononitrile [ch2(cn)2], which is to be isolated by extraction with ether. the solubility of malononitrile in ether at room temperature is 20.0 g/100 ml, and in water is 13.3 g/100 ml. what weight of malononitrile would be recovered by extraction with (a) three 100-ml portions of ether and (b) one 300-ml portion of ether? suggestion: for each extraction, let x equal the weight extracted into the ether layer. in part (a), the concentration in the ether layer is x/100 and in the water layer is (30 x)/300; the ratio of these quantities is equal to k 20/13.3.

A3.37-mg sample of protein was chemically digested to convert its nitrogen into ammonia and then diluted to 100.0 ml. then 10.0 ml of this solution was placed in a 50-ml volumetric flask and treated with 5 ml of phenol solution plus 2 ml of sodium hypochlorite solution. the sample was diluted to 50.0 ml, and the absorbance at 625 nm was measured in a 1.00-cm cuvette and found to be 0.486. for reference, a standard solution was prepared from 10.0 mg of nh4cl (molar mass = 53.49 grams/mole) dissolved in 1.00 l of water. then 10.0 ml of this standard was placed in a 50-ml volumetric flask, treated in the same manner as the unknown, and the absorbance found to be 0.323. finally, a reagent blank was prepared using distilled water in place of unknown, it was treated in the same manner as the unknown, and the absorbance found to be 0.076. calculate the weight percent of nitrogen in the protein.