Choose the species that is incorrectly matched with its electronic geometry. 1. BeBr2 : linear
2. CF4 : tetrahedral
3. NH3 : tetrahedral
4. H2O : tetrahedral
5. PF3 : trigonal bipyramidal

From the options the specie that is incorrectly matched is ( 5 ) ; PF₃ : trigonal bipyramidal

The specie PF₃ is composed of 3 shared pairs and one unshared pair of electrons ( i.e. It has 4 domains ) as seen in the  Lewis structure of  PF₃. therefore  when writing its electronic geometry, it should expressed/written as tetrahedral and not trigonal bipyramidal.

Hence we can conclude that The specie that is incorrectly matched is PF3 : trigonal bipyramidal

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PF3 : trigonal bipyramidal

Explanation:

PF3 has 4 domains around the central phosphorus (3 shared pairs and one lone pair of electrons), thus the electron geometry that has 4 domains is tetrahedral not  trigonal bipyramidal

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