A horizontal cylinder equipped with a frictionless piston contains 785 cm3 of steam at 420.0 K and 125 kPa. A total of 106.2 J of heat is transferred to the steam, causing the steam temperature to rise and the cylinder volume to increase. A constant restraining force is maintained on the piston throughout the expansion, so that the pressure exerted by the piston on the steam remains constant at 125 kPa. The specific enthalpy of steam at 125 kPa varies with temperature approximately as

The content of manganese (mn) in steel was determined spectrophotometrically and with the use of the standard addition method. an unknown sample of mn from a digested steel sample gave an absorbance of 0.185 when analyzed spectrophotometrically. when 5.00 ml of solution containing 95.5 ppm mn was added to 50.0 ml of the unknown steel solution (digested sample), the absorbance was 0.248. calculate the concentration, in parts-per-million (ppm), of mn in the digested steel sample solution.

The arrangement of particles is most ordered in a sample of

Phosphoric acid is a triprotic acid ( =6.9×10−3 , =6.2×10−8 , and =4.8×10−13 ). to find the ph of a buffer composed of h2po−4(aq) and hpo2−4(aq) , which p value should be used in the henderson–hasselbalch equation? p k a1 = 2.16 p k a2 = 7.21 p k a3 = 12.32 calculate the ph of a buffer solution obtained by dissolving 18.0 18.0 g of kh2po4(s) kh 2 po 4 ( s ) and 33.0 33.0 g of na2hpo4(s) na 2 hpo 4 ( s ) in water and then diluting to 1.00 l.