A solution contains 2.2 × 10-3 M in Cu2+ and 0.33 M in LiCN. If the Kf for Cu(CN)42- is 1.0 × 1025, how much copper ion remains at equilibrium?

[Cu²⁺] = 2.01x10⁻²⁶

Explanation:

The equilibrium of Cu(CN)₄²⁻ is:

Cu²⁺ + 4CN⁻ ⇄ Cu(CN)₄²⁻

And Kf is defined as:

Kf = 1.0x10²⁵ = [Cu(CN)₄²⁻] / [Cu²⁺] [CN⁻]⁴

As Kf is too high you can assume all Cu²⁺ is converted in Cu(CN)₄²⁻ -Cu²⁺ is limiting reactant-, the new concentrations will be:

[Cu²⁺] = 0

[CN⁻] = 0.33M - 4×2.2x10⁻³ = 0.3212M

[Cu(CN)₄²⁻] = 2.2x10⁻³

Some [Cu²⁺] will be formed and equilibrium concentrations will be:

[Cu²⁺] = X

[CN⁻] = 0.3212M + 4X

[Cu(CN)₄²⁻] = 2.2x10⁻³ - X

Where X is reaction coordinate

Replacing in Kf equation:

1.0x10²⁵ = [2.2x10⁻³ - X] / [X] [0.3212M +4X]⁴

1.0x10²⁵ = [2.2x10⁻³ - X] / 0.0104858X + 0.524288 X² + 9.8304 X³ + 81.92 X⁴ + 256 X⁵

1.04858x10²³X + 5.24288x10²⁴ X² + 9.8304x10²⁵ X³ + 8.192x10²⁶ X⁴ + 2.56x10²⁷ X⁵ = 2.2x10⁻³ - X

1.04858x10²³X + 5.24288x10²⁴ X² + 9.8304x10²⁵ X³ + 8.192x10²⁶ X⁴ + 2.56x10²⁷ X⁵ - 2.2x10⁻³ = 0

Solving for X:

X = 2.01x10⁻²⁶

As

[Cu²⁺] = X

43.452

step-by-step explanation:

284 times .153 = 43.452

answer: cellular respiration takes in food and uses it to create atp, a chemical which the cell uses for energy. usually, this process uses oxygen, and is called aerobic respiration. it has four stages known as glycolysis, link reaction, the krebs cycle, and the electron transport chain.