For each bond, show the direction of polarity by selecting the correct partial charges. Si-P Si-Cl Cl-P The most polar bond is

Siδ⁺ -- Pδ⁻⁻

Clδ⁻⁻ -- Pδ⁺

Siδ⁺ -- Clδ⁻⁻

Of the mentioned bonds the most polar bond is Si -- Cl

The polarity of the bond primarily relies upon the electronegativity difference between the two atoms that forms the bond. Therefore, if the electronegativity difference between the two atoms that forms the bond is more the bond will be more polar, and if it is less then the bond will be less polar. The electronegativity of the atoms mentioned is Si = 1.8 , P = 2.1 and Cl = 3.00.  

Therefore, the Si - Cl atoms exhibit more electronegativity difference, thus, the Si - Cl bond will be the most polar bond.