In an NMR experiment, shielding refers to the reduced impact of the on a nucleus due to the presence of around the nucleus. Shielding can beby the presence of more electronegative groups around the nucleus. A shielded nucleus appears further whereas a deshielded nucleus appears further in an NMR spectrum.

In an NMR experiment, shielding refers to the reduced impact of the APPLIED MAGNETIC FIELD on a nucleus due to the presence of ELECTRON DENSITYaround the nucleus.

Shielding can be DECREASED by the presence of more electronegative groups around the nucleus.

A shielded nucleus appears further UPFIELD whereas a deshielded nucleus appears further downfield in an NMR spectrum.

Explanation:

1 There is reducece because alot of the electronegative atom binds more and thus reduce the electron density around the nucleus.

While a reduction in electron density bring about more nuclear magnetic field thus it resonates at higher frequency resulting downfield peak.

a electronegativity decreases beacuse the size of nucleus is bigger.

definition

                    entropy is a measure of the randomness or the extent of disorder of a chemical process.

                      enthalpy is a measure of the heat change of a reaction occurring at a constant pressure.

measurement units:

                        entropy is measured in joule per kelvin (jk⁻¹)   whereas enthalpy is measured in joule per mole (jmol⁻¹)

requirements:

                            entropy has no requirements or limits, and its change is measured by the division between the heat change of the chemical process and the temperature.

                              in contrast, enthalpy can only be related to the heat change of the reaction under standard conditions.