I need help with these two chemistry problems I'm completely stuck

Darla claims that the first periodic table developed by mendeleev was not completely accurate, so it is not useful at all. harmony argues that it establish the periodic table we use today, making it more credible. who is correct and why? darla is correct, because a model that has any mistakes should be thrown out. darla is correct, because a good model would not need to change. harmony is correct, because mendeleev’s model had all of the information correct in the first version. harmony is correct, because mendeleev’s model made predictions that came true.

You encounter a solution that is acidic and you decide to test it by adding a small amount of a strong acid. the ph lowers slightly but is approximately unchanged, and still remains acidic. what can you say about the solution? a. it is a buffer solution. b. it is not a buffer solution it is a strong acid solution. d. the solution has been neutralized. e. the solution has excess acid present

What are the first two quantum numbers for the electrons located in subshell 4d? what are the first three quantum numbers for the electrons located in subshell 2s? how many electrons can be held in a sublevel l = 3? how many electrons can be held in the energy level n = 4? how many electrons in an atom can share the quantum numbers n = 4 and l = 3?