State the bond angle and the molecular shape of NH3 and H2O.

Ahypothrticalax type of ceramic material is known to have a density of 2.10 g/cm3 and a unit cell of cubic symmetry with a cell edge length of 0.57 nm. the atomic weights of the a and x elements are 28.5and 30.0 g/mol, respectively. on the basis of this information, which of the following crystal structures is (are) possible for this material: sodium chloride, cesium chloride, or zinc blende

Problem #3 (ch. 1, problem 15)the ideal gas law provides one way to estimate the pressure exerted by a gas on a container. the law isí‘ťí‘ť=푛푛푛푛푛푛푉푉more accurate estimates can be made with the van der waals equationí‘ťí‘ť=푛푛푛푛푛푛푉푉â’푛푛푟푟â’푞푞푛푛2푉푉2where the term nb is a correction for the volume of the molecules and the term an2/v2is a correction for molecular attractions. the values of a and b depend on the type of gas. the gas constant is r, the absolutetemperature is t, the gas volume is v, and the number of moles of gas molecules is indicated by n. if n = 1 mol of an ideal gas were confined to a volume of v = 22.41 l at a temperature of 0â°c (273.2k), it would exert a pressure of 1 atm. in these units, r = 0.0826.for chlorine gas (cl2), a = 6.49 and b = 0.0562. compare the pressure estimates given by the ideal gas law and the van der waals equation for 1 mol of cl2 in 22.41 l at 273.2 k. what is the main cause of the difference in the two pressure estimates, the molecular volume or the molecular attractions?

24. a sports ball is inflated to an internal pressure of 1.85 atm at room temperature (25 °c). if the ball is then played with outside where the temperature is 7.5 °c, what will be the new pressure of the ball? assume the ball does not change in volume nor does any air leak from the ball a) 0.555 atm b) 1.74 atm c) 1.85 atm d) 1.97 atm