Will henry's law not be applicable if the solubility of the gas is very high

No

Explanation:

Henry’s law is a gas law which states that at the amount of gas that is dissolved in a liquid is directly proportional to the partial pressure of that gas above the liquid when the temperature is kept constant. The constant of proportionality for this relationship is called Henry’s law constant (usually denoted by ‘kH‘). The mathematical formula of Henry’s law is given by:

P ∝ C (or) P = kH.C

Where,‘

Limitations of Henry’s Law

periodic trends is an atom that gets larger as the number of electronic shells increase, the radius of atoms increases as you go down a certain group in the periodic table of elements. in general, the size of an atom will decrease as you move from left to right of a certain period.