The first chemists, philosophers like, Aristotle were from which country?

Acalorimeter is to be calibrated: 51.203 g of water at 55.2 degree c is added to a calorimeter containing 49.783 g of water at 23.5c. after stirring and waiting for the system to equilibrate, the final temperature reached is 37.6 degree c. specific heat capacity of water (s = 4.18 j/g∙degree c). calculate the calorimeter constant. (smδt)warm water = -[(smδt)cold water + (calorimeterδtcold water)]

Liquid ammonia is produced at high temperatures and under great pressure in a tank by passing a mixture of nitrogen gas and hydrogen gas over an iron catalyst. the reaction is represented by the following equation. n2(g) + 3h2(g) → 2nh3(g) changing all but one experimental condition will affect the amount of ammonia produced. that condition is a) increasing the concentration of both reactants b) changing the temperature within the tank c) decreasing the pressure within the tank. d) increasing only the amount of nitrogen present.

Now look at the segment of the graph between the two data points marked with black squares. describe how the boiling point and melting point plots behave between these points. be as specific as possible.