Ferric chloride (Iron chloride; FeCl3) reacts with water alkalinity to form an iron hydroxide solid phase. If no alkalinity is present, what will be the pH when 500 mg/L ferric chloride is added to achieve complete coagulation

n+h→nh3

we must remember that nitrogen and hydrogen are both diatomic molecules in their standard gas form. this adjusts the equation to

n2+h2→nh3

now we need to adjust coefficients in order to balance the atoms on each side of the equation. currently we have 2 atoms of nitrogen and 2 atoms of hydrogen on the reactant side and 1 atom of nitrogen and 3 atoms of hydrogen on the product side.

we can balance the hydrogens by placing a coefficient of 2 in front of ammonia and a coefficient of 3 in front of the hydrogen.

n2+3h2→2nh3

this gives us 6 hydrogen on each side and coincidentally the nitrogens now equal 2 on each side.

answer : third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol

explanation :

let us write down the given equations

equation 1 :

equation 2 :

equation 3 :

let us use hess's law to find out which 2 equations can be added to get the third equation.

let us reverse equation 2 and multiply it by 2. the new equation that we get is,

equation 4 :

let us add equation 1 & 4

the above equation is similar to equation 3 but has different value for dhrxn.

therefore third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol