Chemistry help please answer all questions need them by 11:30 thank you!

Harvey kept a balloon with a volume of 348 milliliters at 25.0˚c inside a freezer for a night.  when he took it out, its new volume was 322 milliliters, but its pressure was the same.  if the final temperature of the balloon is the same as the freezer’s, what is the temperature of the freezer? the temperature of the freezer is  kelvins.

Which buffer would be better able to hold a steady ph on the addition of strong acid, buffer 1 or buffer 2? explain. buffer 1: a solution containing 0.10 m nh4cl and 1 m nh3. buffer 2: a solution containing 1 m nh4cl and 0.10 m nh3

Choose an equation that represents an enzyme-catalyzed reaction. (a) enzyme + substrate → enzyme-substrate complex (b) enzyme + substrate ←−→ enzyme + products (c) enzyme + substrate ←−→ enzyme-substrate complex → enzyme + products (d) enzyme + substrate ←−→ enzyme-substrate complex → enzyme-substrate complex + products