what is the difference between polar and ionic? for instance in substances such as vinegar and water.

Vinegar is ionic because ionic bonds form between metal and nonmetal atoms. while water is polar because the oxygen and hydrogen atoms share electrons which forms covalent bonds.

For cyclohexane compounds drawn in a chair conformation:   -axial bonds are vertical  -equatorial bonds are parallel to two bonds within the ring.  thus, as i assume the chair conformation is drawn:   -the x group is in an axial position, as are the five other vertical bonds.  -three axial bonds are on the top face of the ring  -the other three axial bonds are on the bottom face  the position of the second substituent on each ring carbon is equatorial.  gauche groups must be on an adjacent carbon such as carbon 6 and carbon 2, and also gauche groups are rotated by 60 degrees relative to each other.  drawing the newman projections for c1–c2 and c1–c6 aids in visualizing the groups that are gauche to the y group on c1.  click this link and watch some academic videos that may you more understand the topic 

Only one reactant yields 2 or more products. meaning you will only have 1 product and it will break down into 2 or more products. eg. h2o -> h2 + o2