What evidence caused rutherford to change thomson plum pudding model into the nuclear model

As a part of an experiment a student burns propane to produce carbon dioxide and water she remembers that she must follow the law conservation of matter when writing a balanced chemical equation which of these equation adheres to the law of conservation of matter

How many mmols of tris-hcl are there in 100 ml of a 100 mm tris-hcl buffer solution at ph 8.1? note that the 100 mm refers to the sum of tris and tris-hcl concentrations?

What substance has a mass of 9.5g and volume of 2.1cm^3